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Beilstein J. Org. Chem. 2015, 11, 2166–2170, doi:10.3762/bjoc.11.234
Graphical Abstract
Figure 1: Electrochemical oxidation of 1 in deareated (blue) and O2 saturated (red) solutions of CH2Cl2/0.1 M...
Figure 2: The X-ray structures of compounds 1 and 2.
Figure 3: Decrease of the UV absorption band of compound 1 under irradiation (254 nm) in air-saturated CHCl3, ...
Scheme 1: Photoinduced reaction of 1 in O2 saturated CHCl3 under irradiation by intensive sunlight.
Scheme 2: Heterocycle transformations of 1 in air saturated CHCl3 solutions.
Scheme 3: Proposed mechanism of conversion of oxaziridine 4 to 5.
Figure 4: The X-ray structures of compounds 4 and 5.